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Probing influence of rare earth ions (Er3, Dy3 and Gd3

The direct band-gap for undoped magnetite nanoparticles is found to be 2.46 eV which is far larger than the reported band gap for bulk magnetite (0.20 eV) . The increase in the band gap of nanoparticle sample with respect to the bulk magnetite can be attributed to the quantum size effects.

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